Presentation_1_Fabrication of WO3·2H2O/BC Hybrids by the Radiation Method for Enhanced Performance Supercapacitors.PDF (239.54 kB)

Presentation_1_Fabrication of WO3·2H2O/BC Hybrids by the Radiation Method for Enhanced Performance Supercapacitors.PDF

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posted on 13.08.2018 by Fan Yang, Jinzhi Jia, Rui Mi, Xichuan Liu, Zhibing Fu, Chaoyang Wang, Xudong Liu, Yongjian Tang

In this study, we described a facile process for the fabrication of tungsten oxide dihydrate/bamboo charcoal hybrids (WO3·2H2O/BC) by the γ-irradiation method. The structural, morphological, and electrochemical properties of WO3·2H2O/BC hybrids were investigated using X-ray diffraction (XRD), field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), cyclic voltammetry (CV), galvanostatic charge/discharge (GCD), and electrochemical impedance spectroscopy (EIS) techniques. The combination of BC (electrical double layer charge) and WO3·2H2O (pseudocapacitance) created a combined effect, which enhanced the specific capacitance and superior cyclic stability of the WO3·2H2O/BC hybrid electrode. The WO3·2H2O/BC hybrids showed the higher specific capacitance (391 F g−1 at 0.5 A g−1 over the voltage range from −1 to 0 V), compared with BC (108 F g−1) in 6 M KOH solution. Furthermore, the hybrid electrode showed superior long-term performance with 82% capacitance retention even after 10,000 cycles. The experimental results demonstrated that the high performance of WO3·2H2O/BC hybrids could be a potential electrode material for supercapacitors.

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