Datasheet1_Elucidation of Charge Contribution in Iridium-Chelated Hydrogen-Bonding Systems.pdf (5.32 MB)
Download fileDatasheet1_Elucidation of Charge Contribution in Iridium-Chelated Hydrogen-Bonding Systems.pdf
dataset
posted on 2021-08-24, 05:06 authored by Barbora Balónová, Barry A. BlightWe present two iridium complexes 1H+ and 2H+ that contain cationic ligands to extend the knowledge of charge-assisted hydrogen bonding (CAHB), which counts among the strongest non-covalent bonding interactions. Upon protonation, both complexes were converted into new hydrogen-bonding arrays with various selectivity for respective H-bonding partners. This study compares the association strengths of four hydrogen-bonding co-systems, emphasizing the roles of CAHB in supramolecular systems. We determined that the cationic charge in these systems contributed up to 2.7 kJ mol−1 in the H-bonding complexation processes.
History
References
- https://doi.org//10.1021/acs.inorgchem.8b01326
- https://doi.org//10.1080/10610278.2019.1649674
- https://doi.org//10.1021/ja906061v
- https://doi.org//10.1038/nchem.987
- https://doi.org//10.1039/B603089K
- https://doi.org//10.1039/B002061N
- https://doi.org//10.1021/cg049942w
- https://doi.org//10.1016/j.commatsci.2018.02.055
- https://doi.org//10.1021/ja067410t
- https://doi.org//10.1039/A909093B
- https://doi.org//10.1021/ar400019p
- https://doi.org//10.1021/ja802425q
- https://doi.org//10.1016/S0022-2836(99)80018-7
- https://doi.org//10.1021/ja00161a061
- https://doi.org//10.1021/jm100087s
- https://doi.org//10.1016/S0040-4039(02)01455-7
- https://doi.org//10.1021/ja404504m
- https://doi.org//10.1002/poc.3805
- https://doi.org//10.1039/C9NJ00131J
- https://doi.org//10.1246/bcsj.47.767
- https://doi.org//10.1002/anie.20151042310.1002/ange.201510423
- https://doi.org//10.1002/(SICI)1521-3765(19990503)5%3A5<1474%3A%3AAID-CHEM1474>3.0.CO;2-T
- https://doi.org//10.1002/anie.201408487
- https://doi.org//10.1021/acs.cgd.6b00246
- https://doi.org//10.1021/ja00008a002
- https://doi.org//10.1002/1521-3773(20010702)40%3A13<2382%3A%3AAID-ANIE2382>3.0.CO;2-G
- https://doi.org//10.1002/chem.19960021118
- https://doi.org//10.1021/ja028485%2B
- https://doi.org//10.1021/ar00105a004
- https://doi.org//10.1039/c0cs00062k
- https://doi.org//10.1039/C4SC01036A
Usage metrics
Read the peer-reviewed publication
Categories
- Geochemistry
- Biochemistry
- Inorganic Chemistry
- Organic Chemistry
- Nuclear Chemistry
- Medical Biochemistry: Proteins and Peptides (incl. Medical Proteomics)
- Medical Biochemistry and Metabolomics not elsewhere classified
- Environmental Chemistry (incl. Atmospheric Chemistry)
- Analytical Biochemistry
- Cell Neurochemistry
- Electroanalytical Chemistry
- Enzymes
- Organic Green Chemistry
- Physical Organic Chemistry
- Catalysis and Mechanisms of Reactions
- Analytical Chemistry not elsewhere classified
- Food Chemistry and Molecular Gastronomy (excl. Wine)
- Environmental Chemistry