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Data_Sheet_8_Versatile Dibenzothio[seleno]phenes via Hexadehydro-Diels–Alder Domino Cyclization.CDX
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posted on 24.05.2019, 08:04 by Baohua Liu, Qiong Hu, Yinshan Wen, Bo Fang, Xiaoliang Xu, Yimin HuA facile strategy to synthesize highly substituted dibenzoselenophenes and dibenzothiophenes by a domino hexadehydro-Diels–Alder reaction is reported in this article. The formation of three new C–C bonds, one new Caryl–Se/Caryl–S bond, and C–H σ-bond migration via one-pot multiterminal cycloaddition reactions were involved in over three transformations. The target tetracyclic compounds were prepared from tetraynes with a triphenylphosphine selenide or triphenylphosphine sulfide. This reaction played a pivotal role in constructing natural thio[seleno]phene cores, which were highly substituted, and is a robust method for producing fused heterocycles.
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References
- https://doi.org//10.1002/ijc.28224
- https://doi.org//10.1021/ol701815j
- https://doi.org//10.1039/C8QO00470F
- https://doi.org//10.1002/anie.201710592
- https://doi.org//10.1126/scitranslmed.aab1923
- https://doi.org//10.1039/C6CC09732D
- https://doi.org//10.1021/acs.orglett.8b01466
- https://doi.org//10.1021/ol900809w
- https://doi.org//10.1021/jo0700023
- https://doi.org//10.1021/ol300967a
- https://doi.org//10.1002/chem.201701009
- https://doi.org//10.1002/anie.201602374
- https://doi.org//10.1021/acs.jmedchem.5b01183
- https://doi.org//10.1021/jacs.8b10206
- https://doi.org//10.1021/jo902545a
- https://doi.org//10.1021/ja102848z
- https://doi.org//10.1021/acs.jafc.8b00139
- https://doi.org//10.1021/acs.chemmater.6b02042
- https://doi.org//10.1021/ol071258y
- https://doi.org//10.1002/chem.201805938
- https://doi.org//10.1021/acs.orglett.6b03078
- https://doi.org//10.1021/jacs.6b09628
- https://doi.org//10.1021/ja211486f
- https://doi.org//10.1002/anie.201502840
- https://doi.org//10.1021/ja068429z
- https://doi.org//10.1002/anie.201102088
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Categories
- Geochemistry
- Biochemistry
- Organic Chemistry
- Medical Biochemistry: Proteins and Peptides (incl. Medical Proteomics)
- Nuclear Chemistry
- Medical Biochemistry and Metabolomics not elsewhere classified
- Analytical Biochemistry
- Cell Neurochemistry
- Physical Organic Chemistry
- Enzymes
- Organic Green Chemistry
- Environmental Chemistry (incl. Atmospheric Chemistry)
- Catalysis and Mechanisms of Reactions
- Electroanalytical Chemistry
- Analytical Chemistry not elsewhere classified
- Environmental Chemistry
- Food Chemistry and Molecular Gastronomy (excl. Wine)
- Inorganic Chemistry